Summary to follow. 9 syllabus statements · 22 questions · about twenty minutes.
Compiled from the IB Physics guide (first assessment 2025, updated November 2023) and our question bank ·
Specialist review in progress
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Assessed in Paper 1A (multiple choice), Paper 1B (data-based) and Paper 2 (short and extended response). IB Physics guide (first assessment 2025, updated November 2023).
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In preparation: 0 of 9 sections compiled and reviewed. The rest show key terms and common misconceptions from our question bank until they are.
Photoelectric effect HL
Photoelectric effect
The emission of electrons (photoelectrons) from the surface of a metal when electromagnetic radiation of high enough frequency falls on it. Each photoelectron is released by absorbing the whole energy of a single photon. The effect is evidence of the particle nature of light because its main features, a threshold frequency, a maximum kinetic energy that depends on frequency but not on intensity, and emission with no measurable delay, are explained by photons but not by the classical wave theory.
Photon
A quantum (discrete packet) of electromagnetic energy. The energy of one photon is E = hf = hc/λ, where h is the Planck constant (6.63 × 10⁻³⁴ J s), f the frequency and λ the wavelength of the radiation. The energy of a photon depends only on the frequency; the intensity of a beam of given frequency is set by the number of photons arriving per unit area per second.
Features of the photoelectric effect not explained by classical wave theory
In the classical wave theory the energy of light is spread continuously over the wavefront and depends on intensity, not frequency. That theory therefore predicts that light of any frequency should release electrons if it is intense enough or shines for long enough, that more intense light should give electrons more kinetic energy, and that dim light should cause a delay while electrons absorb enough energy. Experiment shows instead that (1) there is a threshold frequency below which no electrons are emitted, however intense the light; (2) the maximum kinetic energy of the photoelectrons increases with frequency and does not depend on intensity; (3) emission begins with no measurable delay even in very dim light. The increase in the number of photoelectrons per second with intensity is explained by both theories and is not evidence against waves.
Students often think More intense light delivers more energy, so each photoelectron receives more energy and leaves the metal faster; a larger stopping potential is then needed. In fact No. The maximum kinetic energy of the photoelectrons depends only on the frequency of the light and the work function of the metal; brighter light releases more electrons per second, each with the same range of energies.
Students often think Electrons gradually absorb energy from the light, so any light will release electrons if it is intense enough or shines long enough, and dim light releases them only after a delay. In fact No. Below the threshold frequency no photoelectrons are emitted at all, however intense the light and however long it shines.
Threshold frequency, f₀ HL
Threshold frequency, f₀
The minimum frequency of electromagnetic radiation that can release photoelectrons from a particular metal. A photon of frequency f₀ has energy exactly equal to the work function: hf₀ = Φ, so f₀ = Φ/h. It is a property of the metal and does not depend on the intensity of the radiation. SI unit: Hz.
Threshold wavelength
The maximum wavelength of electromagnetic radiation that can release photoelectrons from a particular metal, λ₀ = c/f₀ = hc/Φ. Radiation of wavelength LONGER than λ₀ has photons of too little energy and releases no electrons, however intense it is. SI unit: m.
Students often think A longer wave is a bigger wave and carries more energy, so red light has more energetic photons than violet light and the threshold wavelength is a minimum. In fact No. Photon energy is E = hc/λ, so photons of longer wavelength have LESS energy. The threshold wavelength is therefore a maximum: light of longer wavelength releases no photoelectrons.
Students often think Frequency controls how many electrons are released (more waves per second knock out more electrons), while intensity controls how energetic they are. In fact No. It is the other way round: above the threshold, the intensity (number of photons per second) decides how many photoelectrons are emitted per second, and the frequency decides their maximum kinetic energy.
Work function, Φ HL
Work function, Φ
The minimum energy needed to remove an electron from the surface of a particular metal. It is a property of the metal (and the condition of its surface), not of the incident light. It is measured in J or, commonly, in eV (1 eV = 1.60 × 10⁻¹⁹ J).
Einstein's photoelectric equation
E_max = hf − Φ. An electron absorbs the whole energy hf of one photon; at least Φ of this is needed to free the electron from the surface, and the remainder appears as kinetic energy. Electrons that need only the minimum energy Φ to escape leave with the maximum kinetic energy E_max; electrons from deeper in the metal lose more energy and leave with less. A graph of E_max against f is a straight line of gradient h that meets the frequency axis at f₀ and, extended, meets the E_max axis at −Φ.
Maximum kinetic energy of photoelectrons, E_max
The largest kinetic energy of the electrons emitted by photons of a given frequency, E_max = hf − Φ. Emitted electrons have a range of kinetic energies from zero up to E_max. E_max depends on the frequency of the radiation and the work function of the metal, not on the intensity. SI unit: J (often given in eV).
Stopping potential, V_s
The smallest potential difference, applied to make the collecting electrode negative relative to the emitting plate, that reduces the photocurrent to zero. It stops even the most energetic photoelectrons, so eV_s = E_max = hf − Φ. The stopping potential measures E_max, not the work function, and does not depend on the intensity of the radiation. SI unit: V.
Electronvolt, eV
The energy gained by an electron (charge e) when it is accelerated through a potential difference of 1 V: 1 eV = 1.60 × 10⁻¹⁹ J. To convert an energy in eV to joules, multiply by 1.60 × 10⁻¹⁹; to convert joules to eV, divide by 1.60 × 10⁻¹⁹. Energies must be in the same unit before they are added or subtracted.
Photocurrent and saturation current
The current in a photocell produced by photoelectrons reaching the collecting electrode. Above a certain positive potential of the collector all emitted photoelectrons are collected and the current reaches a constant saturation value; making the potential more positive does not increase it further. For radiation of a given frequency above the threshold, the saturation current is proportional to the number of photons arriving per second and so to the intensity.
Students often think Every photon gives the same energy hf and every electron needs Φ to escape, so every photoelectron has kinetic energy exactly hf − Φ. In fact No. They leave with a range of kinetic energies from zero up to a maximum, E_max = hf − Φ.
Students often think The photon's energy hf is given to the electron as kinetic energy, so E_max = hf and depends only on the light, not on the metal. In fact No. At least the work function Φ is used to free the electron from the metal, so the kinetic energy is at most hf − Φ.
Electron diffraction HL
Electron diffraction
The spreading of a beam of electrons into a pattern of maxima and minima after passing through or scattering from a regular structure, such as the atoms of a thin crystalline film. In the electron diffraction tube, electrons accelerated through a few kilovolts pass through a thin graphite film and form bright concentric rings on a fluorescent screen. The angles of the rings match a wavelength λ = h/p, and the rings shrink when the accelerating potential difference is increased. Diffraction is a wave property, so this is evidence of the wave nature of matter.
Minimum intensity in particle scattering
When particles of de Broglie wavelength λ are diffracted by an object of size D, such as a nucleus, the scattered intensity falls to a first minimum at an angle θ given approximately by sin θ ≈ λ/D, as for single-slit diffraction. Measuring this angle for high-energy electrons scattered by nuclei allows the nuclear diameter to be estimated: D ≈ λ/sin θ. A shorter de Broglie wavelength gives the first minimum at a smaller angle.
Students often think Electrons are particles only; the rings are produced by electrons bouncing or being deflected electrically by the atoms, so the pattern is set only by the arrangement of the atoms (and only charged particles show it). In fact No. The rings are a diffraction pattern: their angles match a wavelength λ = h/p, and they change size when the momentum of the electrons changes. This is a wave property of the electrons.
Students often think The fringes or rings arise because the many electrons in the beam interfere with, or push on, one another after passing the target. In fact No. The same pattern builds up when electrons pass through the apparatus one at a time. Each electron's own wave behaviour sets where it can arrive.
Wave–particle duality HL
Wave–particle duality
The principle that both electromagnetic radiation and matter show wave properties, such as diffraction and interference, in some experiments and particle properties, such as localised detection and the transfer of discrete energy and momentum, in others. Neither the classical wave model nor the classical particle model alone describes all their behaviour. It applies to all matter, but the wave properties of large objects are too small to observe.
Students often think An electron is a particle that travels along a wave-shaped (sinusoidal) path, and this wavy motion is what makes it diffract. In fact No. The wave associated with an electron is not a path; it describes where the electron is likely to be detected.
Students often think Only tiny particles such as electrons have wave properties; large objects are purely particles and have no wavelength. In fact Yes. All matter has a de Broglie wavelength, λ = h/p. For large objects it is so short that no diffraction can be observed.
de Broglie wavelength HL
de Broglie wavelength
The wavelength associated with a particle of momentum p: λ = h/p. SI unit: m. For a non-relativistic particle of mass m and kinetic energy E_k, p = mv = √(2mE_k), so λ = h/√(2mE_k); for a particle of charge e accelerated from rest through a potential difference V, E_k = eV. The wavelength is inversely proportional to momentum: the faster or more massive the particle, the shorter its wavelength.
Students often think A bigger or faster particle has a bigger wave, so its de Broglie wavelength is longer. In fact No. λ = h/p: a larger momentum, from a larger mass or speed, gives a SHORTER de Broglie wavelength.
Students often think Particles and photons of the same energy have the same wavelength, so λ = hc/E gives the de Broglie wavelength of a particle, and λ is inversely proportional to its kinetic energy. In fact No. λ = hc/E holds only for photons (massless, E = pc). For a particle with mass, λ = h/p with p = √(2mE_k) in the non-relativistic case.
Compton scattering HL
Compton scattering
The scattering of a high-energy photon, such as an X-ray or gamma-ray photon, by a free (or loosely bound) electron, in which the photon transfers some of its energy and momentum to the recoiling electron. Classical wave theory predicts that scattered radiation has the same wavelength as the incident radiation; Compton found scattered X-rays of longer wavelength, shifted by an amount that depends on the scattering angle exactly as a collision between two particles predicts. This is further evidence of the particle nature of light.
Students often think Scattering does not change the wavelength of radiation; a photon bounces off an electron like a ball off a wall, keeping its energy. In fact No. Compton found scattered X-rays of longer wavelength, shifted by an amount that increases with the scattering angle.
Students often think Only high-frequency radiation such as X-rays and gamma rays behaves as photons; visible light is purely a wave. In fact All electromagnetic radiation consists of photons, including visible light and radio waves; the energy of each photon is hf.
Photon momentum HL
Photon momentum
A photon of wavelength λ carries momentum p = h/λ = hf/c, even though it has no mass. In Compton scattering, energy and momentum are conserved in the photon–electron collision; the scattered photon has less energy, so a lower frequency and a longer wavelength. Its speed is still c.
Students often think The scattered photon has less energy because it is moving more slowly, and slowing down stretches its wavelength. In fact No. A photon always travels at c in a vacuum. It loses energy by having its frequency decreased, so its wavelength increases.
Students often think Some photons are absorbed or lost, so the scattered beam is less intense, and a weaker beam has a longer wavelength. In fact No. The wavelength of each scattered photon is longer because that photon has less energy. The intensity of the beam does not affect the wavelength.
Compton shift HL
Compton shift
The increase in wavelength of a photon scattered through an angle θ by a free electron: λ_f − λ_i = Δλ = (h/m_e c)(1 − cos θ), where m_e is the electron mass. The constant h/m_e c = 2.43 × 10⁻¹² m. The shift is zero at θ = 0°, equals h/m_e c at 90° and is greatest, 2h/m_e c, at 180°. It does not depend on the incident wavelength, so it is a significant fraction of the wavelength only for short-wavelength radiation such as X-rays and gamma rays.
Students often think The Compton shift is proportional to the incident wavelength: the scattered wavelength is longer by a fixed fraction of the incident wavelength. In fact No. Δλ = (h/m_e c)(1 − cos θ) depends only on the scattering angle. For a given angle the shift is the same for any incident wavelength.
Students often think The scattered photon's wavelength is λ_i − Δλ, because a 'shift' reduces the wavelength or because Δλ is read as 'initial minus final'. In fact No. Δλ = λ_f − λ_i is positive, so λ_f = λ_i + Δλ: the scattered wavelength is longer.
Diagnostic a bearings check, not a test
10 questions, one per part of the topic where we can. Answer them, then see which statements you own and which to read.
1 Which observation from photoelectric experiments cannot be explained by the classical wave theory of light? HL
Answer and reasoning
Photoelectrons are emitted without any measurable delay, even in very dim light. — In the wave theory, energy spreads over the wavefront, so in dim light an electron would need time to absorb enough energy to escape. Experiment shows emission begins at once, because a single photon delivers all the energy one electron needs.
More photoelectrons are emitted each second when the light is made much more intense. — A student who counts every photon-model result as evidence against waves picks this. The wave theory also predicts it: more intense light delivers more energy per second and so releases more electrons per second. It does not distinguish the two models.
More photoelectrons are emitted each second when the frequency of the light is raised. — A student who thinks frequency controls the number of electrons picks this. It is not one of the features of the effect: the number of photoelectrons per second is proportional to the number of photons arriving per second, which is set by the intensity, and at a fixed intensity a higher frequency means fewer photons per second, not more. Frequency sets the maximum kinetic energy, E_max = hf − Φ.
Every photoelectron leaves the metal with kinetic energy exactly hf − Φ. — A student who reads Einstein's equation as applying to every electron picks this. It is not observed: photoelectrons have a range of kinetic energies up to a maximum, E_max = hf − Φ, because electrons from below the surface lose extra energy on the way out.
2 Which statement defines the threshold frequency of a metal? HL
Answer and reasoning
The maximum frequency of light that can release photoelectrons from the metal — A student who thinks lower-frequency, longer-wavelength light carries more energy picks this. Photon energy E = hf rises with frequency, so there is a MINIMUM frequency for emission. The threshold WAVELENGTH is the maximum wavelength.
The frequency of light that releases the most photoelectrons per second from the metal — A student who thinks frequency controls the number of photoelectrons picks this. The number emitted per second is set by the intensity (photons per second). The threshold frequency is simply the lowest frequency at which any emission happens.
The frequency below which photoelectrons leave the metal only after a long delay — A student who thinks electrons can build up energy from the light over time picks this. Below the threshold frequency no photoelectrons are emitted at all, however long the light shines, because one photon cannot supply the work function and energy does not accumulate.
The lowest frequency of light that can release photoelectrons from the metal — Below the threshold frequency f₀, each photon has less energy than the work function (hf < Φ), so no electron can be released, whatever the intensity. At f₀, hf₀ = Φ.
3 Ultraviolet radiation of wavelength 200 nm falls on a clean zinc plate. The work function of zinc is 4.30 eV. Take h = 6.63 × 10⁻³⁴ J s, c = 3.00 × 10⁸ m s⁻¹ and e = 1.60 × 10⁻¹⁹ C. What is the stopping potential for the photoelectrons? HL
Answer and reasoning
6.22 V — A student who gives the whole photon energy to the electron uses E_max = hf = 6.22 eV. At least the work function, 4.30 eV, is needed to free the electron, so E_max = 6.22 − 4.30 = 1.92 eV and V_s = 1.92 V.
4.30 V — A student who thinks the stopping potential measures the work function writes eV_s = Φ. The stopping potential stops electrons that have already escaped; it measures their maximum kinetic energy, eV_s = hf − Φ = 1.92 eV.
10.5 V — A student who adds the work function uses E_max = hf + Φ = 6.22 + 4.30 = 10.5 eV. The electron must use energy Φ to escape, so it is subtracted: E_max = 1.92 eV.
Working hf = hc/λ = (6.63 × 10⁻³⁴ J s)(3.00 × 10⁸ m s⁻¹)/(200 × 10⁻⁹ m) = 9.95 × 10⁻¹⁹ J. In eV: 9.95 × 10⁻¹⁹ J / 1.60 × 10⁻¹⁹ J eV⁻¹ = 6.22 eV. E_max = hf − Φ = 6.22 eV − 4.30 eV = 1.92 eV. eV_s = E_max, so V_s = 1.92 V.
4 In an electron diffraction tube, electrons accelerated through a potential difference of a few kilovolts pass through a thin film of graphite and strike a fluorescent screen, where bright concentric rings are seen. How does this experiment provide evidence for the wave nature of matter? HL
Answer and reasoning
The rings form where electrons bounce off the carbon atoms like balls, at particular angles. — A student who treats electrons purely as particles picks this. Particle collisions with atoms would scatter electrons over a spread of angles, not into sharp rings whose size depends on the electrons' momentum as λ = h/p predicts.
The rings are a diffraction pattern, at angles that fit a wavelength λ = h/p for the electrons. — Diffraction is a wave property. The rings are at angles where waves scattered by the regularly spaced carbon atoms reinforce, and those angles match the de Broglie wavelength h/p. Changing the electrons' momentum changes the ring sizes as this wavelength predicts.
Electrons in the beam interfere with one another beyond the film, and the rings mark where they reinforce. — A student who thinks electrons must meet to interfere picks this. The same pattern builds up even when electrons pass through one at a time; each electron's own wave is diffracted by the atoms.
The rings form because each electron follows a wavy path between the rows of atoms. — A student who pictures an electron moving along a wave-shaped path picks this. The electron's wave is not a trajectory; it describes where the electron is likely to be detected, and diffraction of that wave produces the rings.
5 What is meant by the statement that matter exhibits wave–particle duality? HL
Answer and reasoning
Particles such as electrons show wave behaviour, such as diffraction, in some experiments and particle behaviour in others. — Electrons diffract and interfere like waves, yet each is detected at a single point with its whole charge and mass, like a particle. Neither classical model alone describes them; this is also true of light.
Particles such as electrons remain particles, but they travel through space along wave-shaped paths. — A student who pictures a particle following a sinusoidal line picks this. The electron's wave is not a path; it governs where the electron is likely to be detected, and a wavy trajectory could not produce diffraction patterns.
Only the smallest particles, such as electrons, have a wave nature; objects such as dust grains are purely particles. — A student who thinks wave properties belong only to subatomic particles picks this. All matter has a de Broglie wavelength λ = h/p; for large objects it is far too short for diffraction to be observed, but it is not zero.
Particles such as electrons are really spread-out waves, and the particle description no longer applies to them. — A student who replaces the particle model with a classical wave model picks this. Each electron is still detected at a single point, as a particle; duality means that both descriptions are needed.
6 An electron is accelerated from rest through a potential difference of 2.0 kV. Take h = 6.63 × 10⁻³⁴ J s, e = 1.60 × 10⁻¹⁹ C, m_e = 9.11 × 10⁻³¹ kg and c = 3.00 × 10⁸ m s⁻¹, and treat the electron as non-relativistic. What is the de Broglie wavelength of the electron? HL
Answer and reasoning
6.2 × 10⁻¹⁰ m — A student who uses the photon relation λ = hc/E gets (6.63 × 10⁻³⁴ × 3.00 × 10⁸)/(3.20 × 10⁻¹⁶) = 6.2 × 10⁻¹⁰ m. That holds only for photons; for an electron λ = h/p with p = √(2m_eE_k).
3.9 × 10⁻¹¹ m — A student who uses p = √(m_eE_k), leaving out the factor 2, gets 3.9 × 10⁻¹¹ m. From E_k = p²/2m, p = √(2m_eE_k), giving λ = 2.7 × 10⁻¹¹ m.
1.1 × 10⁻²⁰ m — A student who uses E_k = 2000 (the energy in eV) as if it were in joules gets p = √(2 × 9.11 × 10⁻³¹ × 2000) and λ = 1.1 × 10⁻²⁰ m. The kinetic energy is 2000 eV = 3.20 × 10⁻¹⁶ J.
2.7 × 10⁻¹¹ m — E_k = eV = 1.60 × 10⁻¹⁹ × 2000 = 3.20 × 10⁻¹⁶ J. p = √(2m_eE_k) = √(2 × 9.11 × 10⁻³¹ × 3.20 × 10⁻¹⁶) = 2.41 × 10⁻²³ kg m s⁻¹. λ = h/p = 2.7 × 10⁻¹¹ m.
Working E_k = eV = (1.60 × 10⁻¹⁹ C)(2.0 × 10³ V) = 3.20 × 10⁻¹⁶ J. p = √(2m_eE_k) = √(2 × 9.11 × 10⁻³¹ kg × 3.20 × 10⁻¹⁶ J) = 2.41 × 10⁻²³ kg m s⁻¹. λ = h/p = (6.63 × 10⁻³⁴ J s)/(2.41 × 10⁻²³ kg m s⁻¹) = 2.7 × 10⁻¹¹ m.
7 In Compton's experiment, X-rays of a single known wavelength were scattered by electrons in a block of graphite, and the wavelengths of the scattered X-rays were measured at several angles. Which result is evidence for the particle nature of light? HL
Answer and reasoning
The scattered X-rays included a longer wavelength, shifted by an amount that increased with angle. — Classical wave theory predicts scattered radiation of unchanged wavelength. The shifted wavelength, increasing with angle as Δλ = (h/m_ec)(1 − cos θ), is exactly what a collision between a photon of momentum h/λ and an electron predicts.
The scattered X-rays all had the same wavelength as the incident X-rays, at every angle. — A student who pictures a photon bouncing off an electron like a ball off a wall expects no change. This was not observed, and an unchanged wavelength is what the classical WAVE model predicts, so it could not be evidence for photons.
X-rays were scattered in all directions, as balls would be when they hit a target. — A student who takes any particle-like description as evidence picks this. Waves are also scattered in all directions by electrons, so scattering alone does not distinguish the models. The evidence is the angle-dependent increase in wavelength.
The scattered X-rays included a longer wavelength, shifted in proportion to the incident wavelength. — A student who expects the shift to be a fixed fraction of the wavelength picks this. The Compton shift depends only on the scattering angle, Δλ = (h/m_ec)(1 − cos θ), not on the incident wavelength.
8 When an X-ray photon is scattered by a free electron, the scattered photon has a longer wavelength than the incident photon. What is the reason? HL
Answer and reasoning
The photon loses some of its speed in the collision, which stretches its wavelength. — A student who treats a photon like a material particle whose energy depends on speed picks this. A photon always travels at c in a vacuum; its energy falls by a decrease in frequency, which means an increase in wavelength.
The photon transfers some of its energy to the recoiling electron, so its energy hc/λ decreases. — Energy and momentum are conserved in the collision. The electron recoils with kinetic energy taken from the photon, so the scattered photon has less energy E = hc/λ, and therefore a longer wavelength.
Some photons are absorbed, so the scattered beam is weaker and has a longer wavelength. — A student who confuses the intensity of a beam with the energy of each photon picks this. Each scattered photon's wavelength is longer because that photon lost energy to an electron; the number of photons has no effect on the wavelength.
The photon gains energy from the electron, and a photon with more energy has a longer wavelength. — A student who thinks longer wavelength means more energy picks this. E = hc/λ: a longer wavelength means LESS energy. The photon loses energy to the electron, which is initially at rest.
9 Photons are Compton scattered by free electrons. For which scattering angle θ is the increase in the wavelength of the photons greatest? HL
Answer and reasoning
θ = 90°, where the photon turns at right angles — A student who thinks a right-angle deflection is the largest change picks this. At 90°, 1 − cos θ = 1, so Δλ = h/m_ec; at 180°, 1 − cos θ = 2, twice as large.
θ = 0°, where the photon carries straight on — A student who uses cos θ in place of (1 − cos θ) picks this, since cos θ is greatest at 0°. A photon that is not deflected is not changed: 1 − cos 0° = 0, so the shift is zero.
θ = 180°, where the photon is scattered straight back — Δλ = (h/m_ec)(1 − cos θ) is greatest when cos θ = −1, at θ = 180°, where Δλ = 2h/m_ec = 4.85 × 10⁻¹² m. A photon that rebounds straight back has the largest change of momentum and gives the most energy to the electron.
No single angle: the shift is h/m_ec at every angle — A student who takes the constant h/m_ec to be the shift itself picks this. The shift is (h/m_ec)(1 − cos θ), which rises from zero at 0° to 2h/m_ec at 180°.
Working Δλ = (h/m_ec)(1 − cos θ). 1 − cos θ ranges from 0 (θ = 0°) through 1 (θ = 90°) to 2 (θ = 180°), so the shift is greatest at θ = 180°: Δλ_max = 2h/m_ec = 2 × 2.43 × 10⁻¹² m = 4.85 × 10⁻¹² m.
10 A student argues: 'When the intensity of light above the threshold frequency is doubled, the photocurrent doubles. This result proves that light consists of photons.' Which evaluation of this argument is correct? HL
Answer and reasoning
It is valid: a wave model cannot explain why a more intense beam releases more photoelectrons. — A student who treats every photon-model result as evidence against waves picks this. A wave model does explain it: more intense light carries more energy per second. The argument uses a result that does not distinguish the models.
It is flawed: the photocurrent depends on the frequency of the light, not on its intensity. — A student who swaps the roles of frequency and intensity picks this. Above the threshold, the photocurrent is set by the number of photons per second, which is the intensity; the frequency sets the maximum kinetic energy of the photoelectrons.
It is flawed: a wave model also predicts that more intense light releases more photoelectrons each second. — A result is evidence for photons only if the wave model cannot explain it. More intense waves deliver more energy per second and would also release more electrons per second, so this result fits both models. The threshold frequency, E_max independent of intensity and the lack of delay are the results that rule out the wave model.
It is flawed: the photocurrent is fixed by the potential difference across the photocell, not by the light. — A student who applies Ohm's law to a photocell picks this. Once the collector is positive enough to collect every photoelectron, the current is the saturation current, set by the number of photoelectrons emitted per second, which doubles when the intensity doubles.
Read the ones marked not yet in Learn, then Verify.
Verify confirm before you go
12 more questions. Every wrong answer here is a real misconception, and you see why it is wrong straight away.
1 Sodium has a work function of 2.28 eV. Light from a 50 mW red laser of wavelength 650 nm, and then light from a dim violet lamp of wavelength 400 nm delivering only 0.10 mW, falls on a clean sodium surface. Take h = 6.63 × 10⁻³⁴ J s, c = 3.00 × 10⁸ m s⁻¹ and e = 1.60 × 10⁻¹⁹ C. Which light releases photoelectrons from the sodium? HL
Answer and reasoning
Only the red light, from the 650 nm laser — A student who thinks longer-wavelength light carries more energy per photon picks this. E = hc/λ: the 650 nm photons have only 1.91 eV, below the 2.28 eV work function, while the 400 nm photons have 3.11 eV. Light releases electrons only if its wavelength is SHORTER than the threshold wavelength, here 545 nm.
Only the violet light, despite its lower power — Violet photon: E = hc/λ = (6.63 × 10⁻³⁴ × 3.00 × 10⁸)/(400 × 10⁻⁹) = 4.97 × 10⁻¹⁹ J = 3.11 eV, more than 2.28 eV. Red photon: 3.06 × 10⁻¹⁹ J = 1.91 eV, less than 2.28 eV. The power of the laser only sets how many red photons arrive; none of them can free an electron.
Both the red light and the violet light — A student who thinks intense light can release electrons at any frequency picks this. The violet light does release electrons, but the red photons each carry 1.91 eV, below the 2.28 eV work function, and energy from many photons does not accumulate in an electron, however powerful the laser.
Neither the red light nor the violet light — A student who compares photon energies in joules (3.06 × 10⁻¹⁹ J and 4.97 × 10⁻¹⁹ J) directly with 2.28 concludes that both are far too small. Converting first: the violet photons have 4.97 × 10⁻¹⁹ ÷ 1.60 × 10⁻¹⁹ = 3.11 eV, above the work function, so violet light does release electrons.
Working Red: E = hc/λ = (6.63 × 10⁻³⁴ J s)(3.00 × 10⁸ m s⁻¹)/(650 × 10⁻⁹ m) = 3.06 × 10⁻¹⁹ J = (3.06 × 10⁻¹⁹)/(1.60 × 10⁻¹⁹) eV = 1.91 eV < 2.28 eV, so no emission at any power. Violet: E = (6.63 × 10⁻³⁴)(3.00 × 10⁸)/(400 × 10⁻⁹) = 4.97 × 10⁻¹⁹ J = 3.11 eV > 2.28 eV, so photoelectrons are emitted (E_max = 3.11 − 2.28 = 0.83 eV). Equivalently, λ₀ = hc/Φ = (6.63 × 10⁻³⁴)(3.00 × 10⁸)/(2.28 × 1.60 × 10⁻¹⁹) = 5.45 × 10⁻⁷ m = 545 nm; only wavelengths shorter than this release electrons.
2 For each of two metals, P and Q, a student plots the maximum kinetic energy E_max of the photoelectrons against the frequency f of the incident light. Both graphs are straight lines. The line for P meets the frequency axis at 5.0 × 10¹⁴ Hz and the line for Q meets it at 7.0 × 10¹⁴ Hz. Which statement about the two lines is correct? HL
Answer and reasoning
Q's line is steeper, because its gradient is set by the larger work function. — A student who reads the work function from the gradient picks this. The gradient of E_max against f is h for every metal. The work function appears in the intercepts: the line meets the frequency axis at f₀ = Φ/h and, extended, meets the E_max axis at −Φ.
Each line shows the kinetic energy of every photoelectron at that frequency. — A student who thinks every photoelectron leaves with the same energy picks this. Each point on a line is the MAXIMUM kinetic energy, hf − Φ. Φ is the minimum energy needed to remove an electron; electrons from below the surface lose extra energy on the way out and leave with less, down to zero.
Each line would be shifted upwards if light of greater intensity were used. — A student who thinks brighter light gives each photoelectron more energy picks this. E_max = hf − Φ contains no intensity: more intense light of the same frequency releases more electrons per second, not faster ones, so each line stays where it is.
They have equal gradients, each equal to the Planck constant h. — E_max = hf − Φ has the form y = mx + c with gradient h for every metal, so the lines are parallel. They are displaced because Q has the larger work function: Φ = hf₀, so Φ_Q − Φ_P = h × 2.0 × 10¹⁴ Hz.
3 Monochromatic light falls on the emitting plate of a photocell. The potential of the collecting electrode relative to the emitting plate is varied. The photocurrent is zero at −1.2 V and below; it rises as the potential increases and levels off at 3.0 μA above about +2 V. The intensity of the light is then doubled, with its frequency unchanged. Which describes the new current–potential graph? HL
Answer and reasoning
The current is zero at −1.2 V and below, as before, and levels off at 6.0 μA. — Doubling the intensity at the same frequency doubles the number of photons, and so of photoelectrons, per second: the saturation current doubles to 6.0 μA. Each photon still has energy hf, so E_max and the stopping potential are unchanged.
It becomes zero only at a more negative potential, and levels off at 6.0 μA. — A student who thinks brighter light gives electrons more energy picks this. The saturation current does double, but the energy of each photon, hf, is unchanged, so E_max = hf − Φ and the stopping potential of 1.2 V stay the same.
It becomes zero only at a more negative potential, and still levels off at 3.0 μA. — A student who swaps the roles of intensity and frequency picks this, making intensity control the energy and not the number of electrons. It is the reverse: intensity sets the number per second, doubling the saturation current, and frequency sets E_max.
The current is zero at −1.2 V and below, and still levels off at 3.0 μA, set by the potential. — A student who applies Ohm's law to the photocell thinks the potential alone sets the current. The saturation current is the charge of all the photoelectrons emitted per second, which doubles when the number of photons per second doubles.
Working At a fixed frequency each photon has the same energy hf, so E_max = hf − Φ is unchanged and the stopping potential is still 1.2 V (the current is zero at −1.2 V). Doubling the intensity doubles the number of photons, and so of photoelectrons, per second: saturation current = 2 × 3.0 μA = 6.0 μA.
4 In an electron diffraction tube the accelerating potential difference is 3.0 kV and one of the rings on the screen has a radius of 24 mm. The accelerating potential difference is increased to 6.0 kV. Assume the electrons are non-relativistic and that the radius of the ring is proportional to the de Broglie wavelength of the electrons. What is the new radius of this ring? HL
Answer and reasoning
12 mm — A student who uses the photon relation λ = hc/E takes λ ∝ 1/E_k and halves the radius. For a particle with mass, p = √(2mE_k), so λ ∝ 1/√E_k and the radius falls by √2, to 17 mm.
34 mm — A student who thinks faster particles have longer wavelengths multiplies by √2. λ = h/p: the electrons gain momentum, so their wavelength and the ring radius DECREASE, to 24/√2 = 17 mm.
24 mm — A student who thinks the ring pattern is set only by the arrangement of the atoms, as for particles deflected by them, expects no change. The ring angles depend on the electrons' de Broglie wavelength, which decreases as the potential difference increases.
17 mm — E_k = eV and p = √(2m_e eV), so λ = h/p ∝ 1/√V. Doubling V divides λ, and so the radius, by √2: 24 mm/√2 = 17 mm.
Working E_k = eV, so p = √(2m_e eV) and λ = h/√(2m_e eV) ∝ 1/√V. With r ∝ λ: r_new = r × √(V₁/V₂) = 24 mm × √(3.0 kV/6.0 kV) = 24 mm/√2 = 17 mm.
5 In a scattering experiment, a beam of high-energy electrons, each of momentum 2.24 × 10⁻¹⁹ kg m s⁻¹, is directed at a thin carbon target. The intensity of the electrons scattered by the carbon nuclei is measured at different angles to the beam, and the first minimum of intensity is found at 51°. Assume the first minimum occurs at the angle θ where sin θ ≈ λ/D, where λ is the de Broglie wavelength of the electrons and D is the diameter of a nucleus. Take h = 6.63 × 10⁻³⁴ J s. What is the estimated diameter of a carbon nucleus? HL
Answer and reasoning
4.7 × 10⁻¹⁵ m — A student who uses cos 51° = 0.629 in place of sin 51° gets 4.7 × 10⁻¹⁵ m. The first minimum is given by sin θ ≈ λ/D, with θ measured from the direction of the beam.
4.4 × 10⁻¹⁵ m — A student whose calculator is in radian mode gets sin 51 = 0.670 and D = 4.4 × 10⁻¹⁵ m. The angle is in degrees: sin 51° = 0.777.
3.8 × 10⁻¹⁵ m — λ = h/p = 6.63 × 10⁻³⁴/2.24 × 10⁻¹⁹ = 2.96 × 10⁻¹⁵ m. D ≈ λ/sin θ = 2.96 × 10⁻¹⁵/sin 51° = 2.96 × 10⁻¹⁵/0.777 = 3.8 × 10⁻¹⁵ m.
3.0 × 10⁻¹⁵ m — A student who thinks diffraction happens when the wavelength equals the size of the object sets D = λ = 3.0 × 10⁻¹⁵ m. The size is found from the angle of the first minimum: D ≈ λ/sin θ = 3.8 × 10⁻¹⁵ m.
Working λ = h/p = (6.63 × 10⁻³⁴ J s)/(2.24 × 10⁻¹⁹ kg m s⁻¹) = 2.96 × 10⁻¹⁵ m. sin θ ≈ λ/D, so D ≈ λ/sin θ = (2.96 × 10⁻¹⁵ m)/sin 51° = (2.96 × 10⁻¹⁵ m)/0.777 = 3.8 × 10⁻¹⁵ m.
6 Electrons are sent towards a double slit at such a low rate that only one electron is in the apparatus at any time. Each electron is recorded as a single dot on a detector screen. At first the dots seem to be scattered at random, but after many thousands of electrons they form a pattern of bright and dark fringes. What do these results show about each electron? HL
Answer and reasoning
It is deflected by the electrons that went through before it, and this builds up the fringes over time. — A student who thinks the pattern needs electrons to interact with one another picks this. Only one electron is in the apparatus at a time, and the pattern does not depend on the rate; each electron interferes only with its own wave.
It is detected at one point, like a particle, but wave interference sets where it is likely to land. — Each detection is a single dot, which is particle behaviour. Yet the dots build up an interference pattern even though the electrons pass one at a time, so each electron's own wave, passing both slits, sets the probability of where it lands. This is wave–particle duality.
It follows a wavy path from the slits, which carries it to one of the bright fringes. — A student who pictures the wave as a wavy trajectory picks this. There is no such path; the wave determines only the probability of detection at each point, and the dots land at random positions within that distribution.
It spreads out over the whole screen as a wave, and each dot marks the place where most of it arrived. — A student who treats the electron as a spread-out classical wave picks this. Each dot is a whole electron, with all its charge and mass, detected at one point; nothing of it arrives anywhere else.
7 An electron and a proton have the same kinetic energy, and both move at speeds much less than c. The mass of the proton is about 1830 times the mass of the electron. How do their de Broglie wavelengths compare? HL
Answer and reasoning
The proton's wavelength is about 43 times as long as the electron's. — A student who thinks a heavier particle has a longer wavelength inverts the ratio. At equal kinetic energy the proton has the larger momentum, √(2m_pE_k), so it has the SHORTER wavelength.
The electron's wavelength is about 1830 times the proton's. — A student who assumes equal kinetic energy means equal speed uses λ = h/mv with the same v and gets the mass ratio. The lighter electron moves faster, so its momentum is only √1830 ≈ 43 times smaller.
The electron's wavelength is about 43 times the proton's. — λ = h/p = h/√(2mE_k). At equal E_k, λ ∝ 1/√m, so λ_e/λ_p = √(m_p/m_e) = √1830 ≈ 43.
They have equal wavelengths, as the particles have equal energies. — A student who uses the photon relation λ = hc/E for particles thinks equal energies give equal wavelengths. For particles with mass, λ = h/√(2mE_k), which depends on mass as well as energy.
Working λ = h/p and p = √(2mE_k). With equal E_k: λ_e/λ_p = √(2m_pE_k)/√(2m_eE_k) = √(m_p/m_e) = √1830 = 42.8 ≈ 43.
8 A cricket ball of mass 0.16 kg is bowled at 30 m s⁻¹ towards a gap several metres wide between two fielders. Take h = 6.63 × 10⁻³⁴ J s. Which statement explains why no diffraction of the ball is observed? HL
Answer and reasoning
It has no de Broglie wavelength, since it is not a subatomic particle. — A student who thinks only tiny particles have wave properties picks this. λ = h/p applies to any object with momentum; the ball's wavelength is 1.4 × 10⁻³⁴ m, not zero, but far too short to show diffraction.
Its de Broglie wavelength is far too short compared with the width of the gap. — λ = h/p = 6.63 × 10⁻³⁴/(0.16 × 30) = 1.4 × 10⁻³⁴ m. Diffraction is noticeable only when the wavelength is comparable with the gap; here it is about 10³⁴ times smaller, so the spreading is immeasurably small.
It is uncharged, and only charged particles such as electrons diffract. — A student who thinks diffraction of particles is an electrical deflection by atoms picks this. Diffraction is a wave effect: uncharged neutrons, atoms and molecules diffract. The ball does not because its wavelength is so short.
Its de Broglie wavelength does not equal the gap width, and diffraction needs them equal. — A student who thinks diffraction happens only when the wavelength equals the gap picks this. Diffraction is noticeable whenever the wavelength is comparable with the gap, not only when the two are equal. The ball's λ = h/p = 6.63 × 10⁻³⁴/(0.16 × 30) = 1.4 × 10⁻³⁴ m, about 10³⁴ times smaller than the gap, which is why no diffraction is seen.
Working p = mv = 0.16 kg × 30 m s⁻¹ = 4.8 kg m s⁻¹. λ = h/p = (6.63 × 10⁻³⁴ J s)/(4.8 kg m s⁻¹) = 1.4 × 10⁻³⁴ m, about 10³⁴ times smaller than a gap of a few metres.
9 X-rays of wavelength 7.10 × 10⁻¹¹ m are Compton scattered by free electrons. Take h = 6.63 × 10⁻³⁴ J s, m_e = 9.11 × 10⁻³¹ kg and c = 3.00 × 10⁸ m s⁻¹. What is the wavelength of the X-rays scattered through an angle of 120°? HL
Answer and reasoning
6.74 × 10⁻¹¹ m — A student who subtracts the shift gets 7.10 × 10⁻¹¹ − 0.364 × 10⁻¹¹ = 6.74 × 10⁻¹¹ m. Δλ = λ_f − λ_i is positive: the scattered photon has less energy and a LONGER wavelength.
6.98 × 10⁻¹¹ m — A student who uses cos θ in place of (1 − cos θ) gets Δλ = 2.43 × 10⁻¹² × (−0.50) = −1.21 × 10⁻¹² m and λ_f = 6.98 × 10⁻¹¹ m. The factor is 1 − cos 120° = 1.50.
7.15 × 10⁻¹¹ m — A student whose calculator is in radian mode gets cos 120 = 0.814, so 1 − cos θ = 0.186 and Δλ = 4.5 × 10⁻¹³ m. In degrees, cos 120° = −0.50 and 1 − cos θ = 1.50.
7.46 × 10⁻¹¹ m — h/m_ec = 2.43 × 10⁻¹² m. Δλ = 2.43 × 10⁻¹² × (1 − cos 120°) = 2.43 × 10⁻¹² × 1.50 = 3.64 × 10⁻¹² m. λ_f = 7.10 × 10⁻¹¹ + 0.364 × 10⁻¹¹ = 7.46 × 10⁻¹¹ m.
Working h/(m_ec) = (6.63 × 10⁻³⁴ J s)/(9.11 × 10⁻³¹ kg × 3.00 × 10⁸ m s⁻¹) = 2.43 × 10⁻¹² m. Δλ = (h/m_ec)(1 − cos 120°) = 2.43 × 10⁻¹² m × (1 − (−0.50)) = 3.64 × 10⁻¹² m. λ_f = λ_i + Δλ = 7.10 × 10⁻¹¹ m + 0.364 × 10⁻¹¹ m = 7.46 × 10⁻¹¹ m.
10 X-rays of wavelength 7.1 × 10⁻¹¹ m and visible light of wavelength 5.0 × 10⁻⁷ m are each scattered through 90° by free electrons. The Compton shift is easily measured for the X-rays but not for the visible light. Take h/(m_ec) = 2.4 × 10⁻¹² m. What is the reason? HL
Answer and reasoning
The shift is the same for both, but it is a tiny fraction of the visible wavelength. — Δλ = (h/m_ec)(1 − cos 90°) = 2.4 × 10⁻¹² m whatever the incident wavelength. It is 2.4 × 10⁻¹²/7.1 × 10⁻¹¹ ≈ 3% of the X-ray wavelength but only 2.4 × 10⁻¹²/5.0 × 10⁻⁷ ≈ 5 × 10⁻⁶ of the visible wavelength, too small to measure.
The shift is far smaller for visible light, as visible photons carry much less energy. — A student who expects the shift to depend on the photon's energy picks this. The formula contains no incident wavelength: at 90° the shift is 2.4 × 10⁻¹² m for both. Only its size relative to the wavelength differs.
Visible light is scattered only as a wave, since just high-frequency radiation acts as photons. — A student who thinks only X-rays and gamma rays are photons picks this. All electromagnetic radiation consists of photons; visible light even shows the photoelectric effect. Visible photons undergo the same shift, but it is negligible compared with their wavelength.
Visible photons carry more energy than X-rays, so a small energy loss alters their wavelength less. — A student who thinks longer-wavelength photons carry more energy picks this. E = hc/λ: a 500 nm photon has about 7000 times LESS energy than a 0.071 nm X-ray photon. In fact the shift at 90°, 2.4 × 10⁻¹² m, is the same for both; it is simply a tiny fraction of the visible wavelength.
Working Δλ = (h/m_ec)(1 − cos 90°) = 2.4 × 10⁻¹² m × 1 = 2.4 × 10⁻¹² m for both. Fraction of X-ray wavelength: 2.4 × 10⁻¹²/7.1 × 10⁻¹¹ = 0.034 (3%). Fraction of visible wavelength: 2.4 × 10⁻¹²/5.0 × 10⁻⁷ = 4.8 × 10⁻⁶ (about 0.0005%).
11 The photoelectric effect shows that light delivers its energy in quanta of energy hf. A student claims that Compton scattering simply confirms this and gives no additional evidence for the particle nature of light. Which statement about Compton scattering is correct? HL
Answer and reasoning
It shows that a photon also carries momentum h/λ, exchanged with one electron in a collision that conserves momentum and energy. — The photoelectric effect tests only the photon's energy. Compton's results, including the dependence of the shift on angle, are reproduced by treating the event as a two-body collision in which a photon of momentum h/λ and energy hc/λ collides with one electron and both quantities are conserved. This is additional, independent evidence that light behaves as particles.
X-rays are scattered in every direction by the electrons in the target, which a wave could not do, so the X-rays must be particles. — A student who takes any particle-sounding description as evidence picks this. Waves are also scattered in all directions by electrons, so the direction of scattering distinguishes nothing. The evidence lies in the change of wavelength and its dependence on angle.
It shows that X-rays consist of photons, whereas the photoelectric effect shows this only for visible and ultraviolet light. — A student who thinks the photon model applies only to certain parts of the spectrum picks this. The photoelectric effect occurs with X-rays too, and the photon description applies to radiation of every frequency. The new evidence is about momentum, not about which radiation counts as photons.
Photons must have mass, because only a particle with mass can carry momentum into a collision with an electron. — A student who reasons from p = mv that momentum needs mass picks this. A photon has zero rest mass but carries momentum h/λ = E/c; Compton scattering demonstrates that this momentum is exchanged with the electron, not that photons are massive.
12 An X-ray photon of wavelength 2.20 × 10⁻¹¹ m is scattered by a free electron that is initially at rest. The scattered photon has wavelength 2.60 × 10⁻¹¹ m. Take h = 6.63 × 10⁻³⁴ J s and c = 3.00 × 10⁸ m s⁻¹. What is the kinetic energy of the recoiling electron? HL
Answer and reasoning
1.39 × 10⁻¹⁵ J — The photon loses energy to the electron. E_i = hc/λ_i = 9.04 × 10⁻¹⁵ J and E_f = hc/λ_f = 7.65 × 10⁻¹⁵ J, so the electron gains E_i − E_f = 1.39 × 10⁻¹⁵ J as kinetic energy.
9.04 × 10⁻¹⁵ J — A student who treats the event like the photoelectric effect, with the whole photon energy hc/λ_i absorbed by the electron, picks this. In Compton scattering the photon survives with energy hc/λ_f = 7.65 × 10⁻¹⁵ J, and the electron receives only the difference.
4.97 × 10⁻¹⁴ J — A student who substitutes the change in wavelength into E = hc/λ, giving hc/Δλ with Δλ = 4.0 × 10⁻¹² m, picks this. That is five times the incident photon's whole energy, which is impossible. E is inversely proportional to λ, so subtract the two photon energies.
4.64 × 10⁻²⁴ J — A student who uses h/λ as the photon energy picks this. h/λ is the photon's momentum, so h/λ_i − h/λ_f = 4.64 × 10⁻²⁴ kg m s⁻¹ is a momentum, not an energy. The photon energy is hc/λ, a factor c larger.
Working Incident photon energy E_i = hc/λ_i = (6.63 × 10⁻³⁴ J s)(3.00 × 10⁸ m s⁻¹)/(2.20 × 10⁻¹¹ m) = 9.04 × 10⁻¹⁵ J. Scattered photon energy E_f = hc/λ_f = (1.989 × 10⁻²⁵ J m)/(2.60 × 10⁻¹¹ m) = 7.65 × 10⁻¹⁵ J. Energy is conserved and the electron starts at rest, so E_k = E_i − E_f = 9.04 × 10⁻¹⁵ − 7.65 × 10⁻¹⁵ = 1.39 × 10⁻¹⁵ J (about 8.7 keV). The shift of 4.0 × 10⁻¹² m is less than the maximum Compton shift 2h/m_e c = 4.85 × 10⁻¹² m, so the data are physically possible.
That was your twenty minutes. Real practice on E.2 is past-paper questions marked against the mark scheme.
Paper 1A tests it as multiple choice; Paper 1B through data you have not seen before; Paper 2 with short answers and, at HL, extended responses. Look for the command words — outline, explain, compare, evaluate — and give exactly what each asks for.
Compiled from the IB Physics guide (first assessment 2025, updated November 2023) and our question bank · Specialist review in progress. How these pages are made · Free, no account ·